dc.contributor.author |
SAMY |
|
dc.contributor.author |
M.ABU-EL-WAFA |
|
dc.contributor.author |
MOSTAFA A.EL-BEHAIRY |
|
dc.contributor.author |
RAAFAT M. ISSA |
|
dc.contributor.author |
AKILA A. SALEH |
|
dc.date.accessioned |
2023-03-14T06:11:36Z |
|
dc.date.available |
2023-03-14T06:11:36Z |
|
dc.date.issued |
1988-12-15 |
|
dc.identifier.citation |
ABUELWAFA, S. M., ELBEHAIRY, M., Issa, R. M., & Saleh, A. A. (1988). ON THE FORMATION OF MN (II) ANTHRANILIC ACID ANILIDE COMPLEXES-STRUCTURAL ELUCIDATION BY TGA, IR, ELECTRONIC, EPR-SPECTRA AND POTENTIOMETRIC STUDIES. JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 10(4), 464-469. |
en_US |
dc.identifier.issn |
0253-5106 |
|
dc.identifier.uri |
http://142.54.178.187:9060/xmlui/handle/123456789/19096 |
|
dc.description.abstract |
A new series of Mn(1I)-anilide complexes have been prepared and chara¬cterized by elemental analysis, TGA and IR spectra. Electronic and EPR spectra indicate octahedral geometry around the MN(II) ion, where the solvent mole¬cules (H20 or EtOH) occupy axial positions leading to the trans structure.The stability constants of the complexes in 50% dioxane are determined by potentionetric techniques. The values of the conditional stability constants depend on molecular structure. Deviation of the a-log K plots slopes from unity is attributed mainly to steric effect, Tt-electron back donation from the metal on or structural changes in the ligand. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
The Chemical Society of Pakistan |
en_US |
dc.title |
On the Formation of Mn(II) Anthranilic Acid Anilide Complexes. Structural Elucidation by TGA, IR, Electronic, EPR Spectra and Potentiometric Studies |
en_US |
dc.type |
Article |
en_US |