dc.contributor.author |
IFTIKHAR A. AWAN |
|
dc.contributor.author |
M.C.Flowers |
|
dc.date.accessioned |
2023-03-14T06:40:11Z |
|
dc.date.available |
2023-03-14T06:40:11Z |
|
dc.date.issued |
1988-09-20 |
|
dc.identifier.citation |
Awan, I. A., & Flowers, M. C. (1988). KINETICS OF THE THERMAL GAS-PHASE DECOMPOSITION OF 2-ETHOXYPROPENE. JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 10(3), 363-368. |
en_US |
dc.identifier.issn |
0253-5106 |
|
dc.identifier.uri |
http://142.54.178.187:9060/xmlui/handle/123456789/19193 |
|
dc.description.abstract |
Ki netics of the gas phase deconposition of 2-ethoxypropene has been studied over the temperature range 544-635 K at a pressure between 3 and 72 torr. Ethene and propanone, fomed in equimolar amunt ( ± 4 Z), were the major products and accounted for of the total reaction. These products are forned by homogeneous, non-radical , pathways with the high pressure rate constant given by the equation:
-1 12.51±0 .25 -1
= 10 exp(-184.6 ± 2.8 KJ
The other products identified were n-butane, 2-rrethy1prop-2-ena1 , bu tanone and 2-pentanone in ratios of approxirrntely 0.01 0.015 : 0.03 : 0.07 relative to ethene respectively. The kinetics and "Echanims for the formation of these products are discussed in detail . |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
HEJ Research Institute of Chemistry, University of Karachi, Karachi. |
en_US |
dc.title |
Kinetics of the Thermal Gas—phase Decomposition of 2—Ethoxypropene |
en_US |
dc.type |
Article |
en_US |