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Kinetics of the Thermal Gas—phase Decomposition of 2—Ethoxypropene

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dc.contributor.author IFTIKHAR A. AWAN
dc.contributor.author M.C.Flowers
dc.date.accessioned 2023-03-14T06:40:11Z
dc.date.available 2023-03-14T06:40:11Z
dc.date.issued 1988-09-20
dc.identifier.citation Awan, I. A., & Flowers, M. C. (1988). KINETICS OF THE THERMAL GAS-PHASE DECOMPOSITION OF 2-ETHOXYPROPENE. JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 10(3), 363-368. en_US
dc.identifier.issn 0253-5106
dc.identifier.uri http://142.54.178.187:9060/xmlui/handle/123456789/19193
dc.description.abstract Ki netics of the gas phase deconposition of 2-ethoxypropene has been studied over the temperature range 544-635 K at a pressure between 3 and 72 torr. Ethene and propanone, fomed in equimolar amunt ( ± 4 Z), were the major products and accounted for of the total reaction. These products are forned by homogeneous, non-radical , pathways with the high pressure rate constant given by the equation: -1 12.51±0 .25 -1 = 10 exp(-184.6 ± 2.8 KJ The other products identified were n-butane, 2-rrethy1prop-2-ena1 , bu tanone and 2-pentanone in ratios of approxirrntely 0.01 0.015 : 0.03 : 0.07 relative to ethene respectively. The kinetics and "Echanims for the formation of these products are discussed in detail . en_US
dc.language.iso en en_US
dc.publisher HEJ Research Institute of Chemistry, University of Karachi, Karachi. en_US
dc.title Kinetics of the Thermal Gas—phase Decomposition of 2—Ethoxypropene en_US
dc.type Article en_US


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