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Synthesis and Structural Aspects of 2-Chloro-N, N-dimethylbenzylamine and its Complexes with Mo(CO)6 and W (CO)6

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dc.contributor.author TARIQ MAHMUD
dc.contributor.author MUHAMMAD IMRAN
dc.contributor.author JAVED IQBAL
dc.contributor.author VlCKIE MCKEE
dc.date.accessioned 2023-09-20T03:37:04Z
dc.date.available 2023-09-20T03:37:04Z
dc.date.issued 2009-08-20
dc.identifier.citation Muhmmad, T., Imran, M., Iqbal, J., & Mckee, V. (2009). Synthesis and structural aspects of 2-chloro-N, N-dimethylbenzylamine and its complexes with Mo (CO)/sub 6/W (CO)/sub 6. Journal of the Chemical Society of Pakistan, 31. en_US
dc.identifier.issn 0253-5106
dc.identifier.uri http://142.54.178.187:9060/xmlui/handle/123456789/19661
dc.description.abstract A new ligand 2-chloro-N,N-dimethylbenzylamine has been synthesized by the amination of 2-chloro-benzyl bromide. The synthesized ligand was further reacted with W(CO)6 and Mo(CO)6 to yield 2-chloro-N,N-dimethylbenzylamine W(CO)5 and 2-chloro-N,N-dimethylbenzylamine Mo(CO)6 complexes, respectively. The structures of the ligand as well as its metal complexes were established on the basis of physico-analytical, infrared, 1H NMR and 13C NMR spectroscopic data. On the basis of this data, it has been concluded that the ligand has monodentate nature and coordinate with metal through nitrogen atom and replaces one CO molecule to maintain the charge density on the metal center. en_US
dc.description.sponsorship The chemical society of Pakistan is an approved society from the PSF. en_US
dc.language.iso en en_US
dc.publisher HEJ Research Institute of Chemistry, University of Karachi, Karachi. en_US
dc.title Synthesis and Structural Aspects of 2-Chloro-N, N-dimethylbenzylamine and its Complexes with Mo(CO)6 and W (CO)6 en_US
dc.type Article en_US


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