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Synthesis and Spectral Characterization of Mono- and Homodinuclear Complexes of Co(II), Ni(II), and Cu(II) with a Compartmental Hexadentate Schiff Base Ligand Derived from 3-Formylsalicylic Acid

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dc.contributor.author ESAM ABD El-MALEK
dc.contributor.author ABD-ALLAH ORABI
dc.date.accessioned 2023-10-02T04:10:34Z
dc.date.available 2023-10-02T04:10:34Z
dc.date.issued 2010-12-02
dc.identifier.citation Malek, E. A., & Orabi, A. A. (2010). Synthesis and spectral characterization of mono-and homodinuclear complexes of Co (II), Ni (II), and Cu (II) with a compartmental hexadentate schiff base ligand derived from 3-formylsalicylic acid. Journal of the Chemical Society of Pakistan, 32. en_US
dc.identifier.issn 0253-5106
dc.identifier.uri http://142.54.178.187:9060/xmlui/handle/123456789/19740
dc.description.abstract Reaction between 3-formylsalicylic acid and 4,5-dichloro-1,2-phenylenediamine gave a compartmental hexadentate Schiff base (H4fsacph) with an N₂O₄ donor frame involving an inner N₂O₂ set of donors and an outer set of O₂O₂ donors. Three mononuclear complexes of the form M(H₂fsacph)(H₂O)₂ (M = Co(II), Ni(II), Cu(II), and three homodinuclear complexes M'2(fsacph)(H2O)2 (M' = Co(II), Ni(II)) and Cu2(fsacph) were isolated and analyzed by physico-chemical techniques. The metal ions have been found to occupy the outer coordination site in the mononuclear complexes and occupy both sites in the dinuclear complexes. en_US
dc.description.sponsorship The chemical society of Pakistan is an approved society from the PSF. en_US
dc.language.iso en en_US
dc.publisher Karachi: The Chemical Society of Pakistan en_US
dc.title Synthesis and Spectral Characterization of Mono- and Homodinuclear Complexes of Co(II), Ni(II), and Cu(II) with a Compartmental Hexadentate Schiff Base Ligand Derived from 3-Formylsalicylic Acid en_US
dc.type Article en_US


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