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The Synthesis of N,S-Substituted compounds from the reactions of 2-Nitrohalobuta-1,3-diene with Mercaptocoumarin

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dc.contributor.author Fatma GÜLAY KIRBASLAR
dc.contributor.author FİLİZ AVCI
dc.contributor.author CEMİL İBİS
dc.date.accessioned 2023-10-12T05:37:13Z
dc.date.available 2023-10-12T05:37:13Z
dc.date.issued 2011-10-26
dc.identifier.citation Kirbaslar, F. G., Avci, F., & Ibis, C. (2011). The Synthesis of N, S-Substituted compounds from the reactions of 2-Nitrohalobuta-1, 3-diene with Mercaptocoumarin. Journal of the Chemical Society of Pakistan, 33(5), 751-757. en_US
dc.identifier.issn 0253-5106
dc.identifier.uri http://142.54.178.187:9060/xmlui/handle/123456789/19828
dc.description.abstract 4-Bromo-1,3,4-trichloro-2-nitro-1-(7-coumarinthio-4-methyl)-1,3-butadiene (3), and 4-Bromo-3,4-dichloro-2-nitro-1,1-bis (7-coumarinthio-4-methyl)-1,3-butadiene (4) were synthesized from the reactions of 4-bromo-1,1,3,4-tetrachloro-2-nitro-1,3-butadiene (1) with 7-mercapto-4-methylcoumarin (2). Afterwards, new N,S- substituted dienes( 6a-j, 8a-d, 10 and 12) were obtained by the reactions of derivatives of piperazine [4-(fluorophenyl) piperazine, phenyl piperazine, 1-(2-methoxyphenyl)-piperazine, ethoxycarbonyl piperazine, formylpiperazine,2-(fluorophenyl)-piperazine, 4-(nitrophenyl)-piperazine, diphenylmethyl piperazine, 4-(hydroxyphenyl)- piperazine, 4-(hydroxyphenyl)- piperazine]; piperidine [4-methyl piperidinyl, 4-benzyl piperidinyl, 4-hydroxy piperidinyl]; morpholin and 1,4-dioxoazospiro [4,5] decan with the mono(thio)substituted nitrodien compound 3. Structures of the novel compounds were characterized by using microanalysis, FT-IR, UV-Vis, 1H-NMR, APT and MS spectroscopy methods. en_US
dc.description.sponsorship The chemical society of Pakistan is an approved society from the PSF. en_US
dc.language.iso en en_US
dc.publisher HEJ Research Institute of Chemistry, University of Karachi, Karachi. en_US
dc.title The Synthesis of N,S-Substituted compounds from the reactions of 2-Nitrohalobuta-1,3-diene with Mercaptocoumarin en_US
dc.type Article en_US


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