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Novel Ru-Complex of Methyldiphenylcyclopentadienylide

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dc.contributor.author SYEDA ROBINA GILANI
dc.contributor.author ZAID MAHMOOD
dc.date.accessioned 2023-11-07T05:01:21Z
dc.date.available 2023-11-07T05:01:21Z
dc.date.issued 2010-08-20
dc.identifier.citation Gilani, S. R., & Mehmood, A. (2010). Novel Ru-complex of methyldiphenylcyclopentadienylide. Journal of the Chemical Society of Pakistan, 32(4), 449-461. en_US
dc.identifier.issn 0253-5106
dc.identifier.uri http://142.54.178.187:9060/xmlui/handle/123456789/19920
dc.description.abstract Ylide CpPMePh₂ was synthesized by the deprotonation of Ylide salt of iodide by using different deprotonating agent like n butyl Li, NaH, (CH₃)₂N Li, isopropyl Li and ((CH₃)₃Si)₂N.Li. Out of all these deprotonating agents only ((CH₃)₃Si)₂N.Li gave pure and better yield. Its complex of Ru was synthesized. A RuCl₂(PPh₃)₃complex reacted with the freshly synthesized Ylide gave successful required ruthenium complex. The synthesized [Ru(PPh₃)₃(CpPMePh₂)₂]Cl₂ complex was analyzed and verified by ₁H and ₃₁P NMR. en_US
dc.description.sponsorship The chemical society of Pakistan is an approved society from the PSF. en_US
dc.language.iso en en_US
dc.publisher HEJ Research Institute of Chemistry, University of Karachi, Karachi. en_US
dc.title Novel Ru-Complex of Methyldiphenylcyclopentadienylide en_US
dc.type Article en_US


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