dc.contributor.author |
SYEDA ROBINA GILANI |
|
dc.contributor.author |
ZAID MAHMOOD |
|
dc.date.accessioned |
2023-11-07T05:01:21Z |
|
dc.date.available |
2023-11-07T05:01:21Z |
|
dc.date.issued |
2010-08-20 |
|
dc.identifier.citation |
Gilani, S. R., & Mehmood, A. (2010). Novel Ru-complex of methyldiphenylcyclopentadienylide. Journal of the Chemical Society of Pakistan, 32(4), 449-461. |
en_US |
dc.identifier.issn |
0253-5106 |
|
dc.identifier.uri |
http://142.54.178.187:9060/xmlui/handle/123456789/19920 |
|
dc.description.abstract |
Ylide CpPMePh₂ was synthesized by the deprotonation of Ylide salt of iodide by using different deprotonating agent like n butyl Li, NaH, (CH₃)₂N Li, isopropyl Li and ((CH₃)₃Si)₂N.Li. Out of all these deprotonating agents only ((CH₃)₃Si)₂N.Li gave pure and better yield. Its complex of Ru was synthesized. A RuCl₂(PPh₃)₃complex reacted with the freshly synthesized Ylide gave successful required ruthenium complex. The synthesized [Ru(PPh₃)₃(CpPMePh₂)₂]Cl₂ complex was analyzed and verified by ₁H and ₃₁P NMR. |
en_US |
dc.description.sponsorship |
The chemical society of Pakistan is an approved society from the PSF. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
HEJ Research Institute of Chemistry, University of Karachi, Karachi. |
en_US |
dc.title |
Novel Ru-Complex of Methyldiphenylcyclopentadienylide |
en_US |
dc.type |
Article |
en_US |