Abstract:
The Himalayan Foreland Basin (HFB) is one of the largest and dynamic terrestrial
basins, stretching between the northwestern and northeastern Himalayas before arching
southward to the Arabian Sea in the west and the Indian Ocean in the east. Molasse
sediments eroded from the Himalayan orogen, representing the post-Eocene sedimentary
record of the collision of the Indian and Eurasian plates occur in this basin from Pakistan
through India to Nepal. In Pakistan, this sedimentary sequence is well preserved and
exposed in the Kohat and Potwar plateaus other than Sulaiman and Kirthar ranges. The
source area, sedimentation pattern, drainage organization, tectonic and climatic conditions
generally differ at sub-basin level. For present study, the Neogene molasse sequence of
the southwestern Kohat plateau is selected, which constitutes the westernmost deformed
part of the HFB. Here, the Neogene molasse sequence consists of the Kamlial, Chinji and
Nagri formations. All these formations are composed of sandstones, mudstones and
conglomerates.
On the basis of field observations and presence of various sedimentary structures,
different lithofacies of the Kamlial Formations are identified, namely; Channel
Conglomerates Facies (K1), Cross-bedded Sandstone Facies (K2), Interbedded Mudstone,
Sandstone and Siltstone Facies (K3) and Mudstone Facies (K4). In Chinji Formation,
based on various sedimentary structures, lithofacies identified include; Cross-bedded
Channel Sandstone Facies (C1), Cross-bedded and Cross-laminated Sandstone Facies
(C2), Interbedded Mudstone, Siltstone and Sandstone Facies (C3) and Mudstone Facies
(C4). Alike, lithofacies identified in the Nagri Formation include Channel Conglomerate
Facies (N1), Cross-bedded Channel Sandstone Facies (N2), Interbedded Sandstone,
Siltstone and Mudstone Facies (N3) and Mudstone Facies (N4).
The above mentioned facies propose that the Kamlial Formation was possibly
deposited by sandy bedload or major mixed load river, the Chinji Formation by mixed-
load rivers with significant fine suspended sediment and the Nagri Formation by sandy
bedload rivers. The floodplain deposits of the Chinji Formation seem to be deposited by
suspended-load rivers during major flood events. Low lateral and vertical connectivity of
the sandstone bodies suggests high subsidence rates. The change from thick channel
sandstones of Kamlial Formation to dominantly overbank accumulation with minor, thin,
channel-sandstone lenses of the Chinji Formation could either be due to a change in
climate or palaeodrainage of the area. Again a major change from mudstone-siltstone
facies-dominant Chinji Formation to channel sandstone facies-dominant Nagri Formation
occurs, which might reflect one or more factors including (1) low subsidence rates, or (2)
arid climatic regime and limited vegetation, or (3) strongly seasonal discharge resulting in
flash flooding.
Detailed petrographic studies of representative sandstone samples from three
different sections reveal that the Kamlial, Chinji and Nagri formations contain abundant
quartz with subordinate feldspars and variable proportions of lithic grains.
Monocrystalline quartz dominates over polycrystalline quartz in all the three studied
formations. The feldspar content mostly ranges from 18 to 30%, 24 to 28% and 16 to 36%
in the Kamlial, Chinji and Nagri sandstones, respectively. The abundance of lithic grains
shows a wide range of variation (4 to 35%). Although the lithics are mainly sedimentary,
but fragments of volcanic and low-grade metamorphic rocks also occur in appreciable
amounts. Micas, including both muscovite and biotite, are generally less than 10 % of the
total detrital grains. The observed heavy minerals include epidote, monazite, apatite,
garnet, zircon, rutile and brown hornblende. The crystals of zircon, monazite, rutile,
epidote and mica also occur as tiny inclusions in quartz grains.
viOn the basis of modal composition, sandstones of the Kamlial, Chinji and Nagri
formations fall into the groups of feldspathic and lithic arenites indicating to be the
products of feldspar-rich crystalline rocks and rugged high-relief source areas,
respectively. The presence of appreciable amount of feldspars in the sandstone samples
favors either high relief or arctic climate at the source area. The overall variation in the
relative abundance of different types of quartz grains (monocrystalline including both
non-undulatory and undulatory types and polycrystalline containing 2-3 and >3
subgrains) shows contribution from both medium-high grade and low-grade metamorphic
rocks provenance for sandstones of the Kamlial, Chinji and Nagri formations, supported
by the consistent presence of minerals like mica, epidote and garnet as well as relative
dominance of polycrystalline quartz grains composed of 2-3 crystals (Qp 2-3 ). Alike, the
presence of illite in mudstone also suggests a source area composed of metamorphic and
sedimentary rocks. On the other hand, the average contents of different types of quartz
grains from the Kamlial, Chinji and Nagri formations show granitic and/or gneissic
source. The greater abundance of alkali feldspar than plagioclase further supports this
conclusion. The relatively greater abundance of monocrystalline quartz also suggests that
the presence of granitic and volcanic rocks in the source areas cannot be ruled out, or else
the quartz grains have traveled a longer distance of transportation. Furthermore, the inter-
sectional variation in modal composition and types of quartz grains in both the Kamlial
and Chinji sandstones suggest a strong spatial control on their deposition.
Petrographic results of the studied sandstones were also processed using different
provenance discriminatory diagrams suggesting Magmatic arc, Recycled Orogens and a
mixed provenance for the Kamlial, Chinji and Nagri formations.
Similarly, geochemical data of the major element oxides of the sandstone was
used for classification and provenance determination applying different tectonic
discriminatory plots. Sandstone of the Kamlial, Chinji and Nagri formations
predominantly classify as litharenite and Fe-sand. The shift of sandstone to various fields
in classification is due to a wide range in the variation of relative proportion of matrix,
feldspar and lithic components. Different provenance discriminatory plots suggest
continental island arc and Active Continental Margin (ACM) provenance for the
sandstone of the three studied formations of southwestern Kohat. Similarly,
discriminatory plot of SiO 2 vs log (K 2 O/Na 2 O) indicate a dominant influx from ACM for
the studied sandstone. Other geochemical parameters like Fe 2 O 3 +MgO, TiO 2 and
Al 2 O 3 /SiO 2 and the contents of the major element oxides except MnO of the Neogene
molasse sandstone show major provenance from continental island arc and partial influx
from ACM settings. Furthermore, the Th/U ratio of the Neogene molasse sequence is
lower than the UCC and PAAS, which also show that these sediments are first cycled in
origin; however, Zr/Sc ratio proposes minor contribution from recycled sedimentary
sources.
In regional tectonic scenario of the study area, it is assumed that the recycled
orogen sediments are sourced from the Himalayan tectonic units, the active continental
margin orogen sediments from the Asian active continental margin (the Trans-Himalaya
and Karakoram) and the magmatic arc orogen sediments from the Kohistan-Ladakh arc.
Values of the Chemical Index of Alteration (CIA) of the Neogene sandstone
(mostly 64 to 76) and mudstone (mostly 70 to 80) suggest moderate to slightly intense
weathering of these sediments, respectively. However, Index of Compositional
Variability (ICV) values and lower contents of Rb and Cs than UCC and PAAS of the
mudstone indicate relatively moderate weathering. The more abundance of feldspar
(plagioclase) than clay minerals in the mudstone suggests high denudation rates or high
relief or limited chemical weathering in the source area(s). The presence of illite in the
viimudstone suggests cold and dry glacier conditions whereas kaolinite indicates warm and
humid conditions. This conclusion either favors a source region of vast area that had
different climates in different parts, or major shifts in extreme climatic conditions. Red
coloration of the Neogene mudstone of the Kohat Plateau most probably indicates
deposition under hot, semi-arid and oxidizing diagenetic conditions. Furthermore, the
values of the authigenic U, and ratios of U/Th, V/Cr, Cu/Zn and Ni/Co of the Neogene
molasse sediments show that these sediments were deposited in oxidizing conditions.
Greater abundance of alkali feldspar than plagioclase in the Neogene sandstone of
the Kohat Plateau, and dominance of plagioclase in the associated mudstone suggest
granitic and mafic/ultramafic sources for these sediments, respectively. However, the
lower values of Zr, Nb and Y, and ratios of the Ba/Sc, Ba/Co, Cr/Zr, Sc/Th and Y/Ni in
sandstone and mudstone indicate the consistent presence of basic/mafic phases in the
source area, still values of La/Th, La/Sc, Th/Zr and binary plot of Th/Co vs La/Sc propose
provenance similar to Upper Continental Crust (UCC)/Post Archaen Australian Shale
(PAAS)/felsic rocks. Generally, there exist a significant positive correlation of TiO 2 , Zr,
Rb and V with Al 2 O 3 indicating their association with clay minerals and associated
phases.